Halogen bonding based recognition processes: A world parallel to hydrogen bonding

被引：1742

作者：

Metrangolo, P ^{[1
]}

Neukirch, H

Pilati, T

Resnati, G

机构：

[1] Politecn Milan, Milan, Italy

[2] Dept Chem Mat & Chem Engn Giulio Natta, I-20131 Milan, Italy

[3] CNR, Inst Mol Sci, I-20133 Milan, Italy

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2005年 / 38卷 / 05期

关键词：

D O I：

10.1021/ar0400995

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Halogen bonding is the noncovalent interaction between halogen atoms (Lewis acids) and neutral or anionic Lewis bases. The main features of the interaction are given, and the close similarity with the hydrogen bonding will become apparent. Some heuristic principles are presented to develop a rational crystal engineering based on halogen bonding. The focus is on halogen-bonded supramolecular architectures given by halocarbons. The potential of the interaction is shown by useful applications in the field of synthetic chemistry, material science, and bioorganic chemistry.

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页码：386 / 395

页数：10

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