Nitrido and imido transition metal complexes of Groups 6-8

被引：312

作者：

Eikey, RA ^{[1
]}

Abu-Omar, MM ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2003年 / 243卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

nitrido; imido; Group; 6; metals; 7; 8; MIXED-LIGAND COMPLEXES; NITROGEN ATOM-TRANSFER; RAY CRYSTAL-STRUCTURES; TECHNETIUM(V) PHENYLIMIDO COMPLEX; N BOND-CLEAVAGE; 3-COORDINATE MOLYBDENUM(III); RHENIUM(V) COMPLEXES; MOLECULAR-STRUCTURES; STRUCTURAL-CHARACTERIZATION; PHOTOPHYSICAL PROPERTIES;

D O I：

10.1016/S0010-8545(03)00048-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review summarizes the syntheses and reactivities of Groups 6, 7, and 8 metal nitrido and imido complexes reported until August 2002. We begin with a general description of the bonding and reactivity of transition metal nitrido and imido complexes followed by a discussion of the common synthetic routes. The main focus of the review is the survey of the nitrido and imido complexes of Groups 6-8 with an emphasis on their synthesis and reactivity. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：83 / 124

页数：42

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