Statistics of single-molecule surface enhanced Raman scattering signals: Fluctuation analysis with multiple analyte techniques

被引：121

作者：

Etchegoin, P. G. ^{[1
]}

Meyer, M. ^{[1
]}

Blackie, E. ^{[1
]}

Le Ru, E. C. ^{[1
]}

机构：

[1] Victoria Univ Wellington, Sch Chem & Phys Sci, MacDiarmid Inst Adv Mat & Nanotechnol, Wellington, New Zealand

来源：

ANALYTICAL CHEMISTRY | 2007年 / 79卷 / 21期

关键词：

D O I：

10.1021/ac071231s

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The mathematical background, based on a variation of the principal component analysis (PCA) method, is developed for the understanding of fluctuating multiple analyte single-molecule (SM) surface enhanced Raman scattering (SERS) signals; with emphasis on the bianalyte SERS technique developed recently. The method and its significance are presented to provide a systematic framework with which several aspects of the statistics of SM-SERS signals can be analyzed in general. We also apply the method to a concrete example of bianalyte statistics in silver colloidal solutions and discuss related topics around experimental issues and the interpretation of single-molecule SERS data.

引用

页码：8411 / 8415

页数：5

共 16 条

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