Coupling Mo2n+ units via dicarboxylate bridges

被引：60

作者：

Cotton, FA

Lin, C

Murillo, CA

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[2] Texas A&M Univ, Mol Struct & Bonding Lab, College Stn, TX 77842 USA

[3] Univ Costa Rica, Dept Chem, San Jose, Costa Rica

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 19期

关键词：

D O I：

10.1039/a806161k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds Mo-2(DArF)(3)(O2CC2H5) 1, (DArF)(3)Mo-2-(O2CCO2)Mo-2(DArF)(3) 2 and (DArF)(3)Mo-2(O2CC6F4CO2)Mo-2(DArF)(3) 3 (DArF = N,N'-diarylformamidinate, Ar = p-anisyl) have been selectively prepared in good yield from the reactions of Mo-2(DArF)(3)Cl-2 and the corresponding carboxylate salts in the presence of NaHBEt3; their crystal structures, electronic spectra and electrochemistry have been studied.

引用

页码：3151 / 3153

页数：3

共 6 条

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