A superoxodicopper(II) complex oxidatively generated by a reaction of Di-μ-hydroxodicopper(II) complex with hydrogen peroxide

被引：17

作者：

Kodera, M ^{[1
]}

Tachi, Y

Hirota, S

Katayama, K

Shimakoshi, H

Kano, K

Fujisawa, K

Moro-oka, Y

Naruta, Y

Kitagawa, T

机构：

[1] Doshisha Univ, Fac Engn, Dept Mol Sci & Technol, Kyoto 61003, Japan

[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 46401, Japan

[3] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 227, Japan

[4] Kyushu Univ, Inst Fundamental Res Organ Chem, Higashi Ku, Fukuoka 812, Japan

[5] Okazaki Natl Res Inst, Inst Mol Sci, Okazaki, Aichi 444, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 05期

关键词：

D O I：

10.1246/cl.1998.389

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Di-mu-hydroxodicopper(II) complex with a hexapyridine dinucleating ligand, [Cu-2(OH)(2)(hexpy)](CF3SO3)(2) (hexpy = 1,2-bis[2-(bis(2-pyridyl)methyl)-6-pyridyl]ethane), reacts with H2O2 in MeCN/CH2Cl2 to give a superoxodicopper(Il) complex.

引用

页码：389 / 390

页数：2

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