Continuous hydrothermal synthesis of nanometric BaZrO3 in supercritical water

被引：31

作者：

Aimable, A. ^{[1
]}

Xin, B. ^{[1
]}

Millot, N. ^{[1
]}

Aymes, D. ^{[1
]}

机构：

[1] Univ Bourgogne, CNRS, UMR 5209, Inst Carnot Bourgogne, F-21078 Dijon, France

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2008年 / 181卷 / 01期

关键词：

powders-chemical preparation; grain size; BaZrO3; supercritical water synthesis;

D O I：

10.1016/j.jssc.2007.11.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nanocrystalline barium zirconate (BaZrO3) was synthesized using a hydrothermal synthesis process working in supercritical conditions and in a continuous way. By this method, we succeeded in the continuous and rapid production of nanopowders. As a preliminary work three barium precursors have been investigated: barium hydroxide (Ba(OH)(2)), barium acetate (Ba(CH3COO)(2)) and barium nitrate (Ba(NO3)(2)). Two of them (Ba(CH3COO)(2) and Ba(NO3)(2)) led to the pure perovskite phase. Then an experimental design has been conducted in order to determine the influence of the experimental parameters on the crystallinity and the grain size of the final product. (c) 2007 Elsevier Inc. All rights reserved.

引用

页码：183 / 189

页数：7

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