Head-To-Tail and Heteroleptic Pentanuclear Circular Helicates

被引：33

作者：

Allen, Kirsty E. ^{[1
]}

Faulkner, Robert A. ^{[1
]}

Harding, Lindsay P. ^{[1
]}

Rice, Craig R. ^{[1
]}

Riis-Johannessen, T. ^{[2
]}

Voss, Melanie L. ^{[1
]}

Whitehead, Martina ^{[1
]}

机构：

[1] Univ Huddersfield, Dept Chem & Biol Sci, Huddersfield HD1 3DH, W Yorkshire, England

[2] EPFL SB ISIC LCS, BCH 3307, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 37期

关键词：

copper; helical structures; heteroleptic complexes; N; S ligands; supramolecular chemistry; SELF-RECOGNITION; LIGAND STRANDS; COMPLEXES; DINUCLEAR; UNITS;

D O I：

10.1002/anie.201003342

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Everybody form a circle: Careful design of ligand strands and their reaction with Cu2+ ions leads to the formation of the title helicates. Incorporation of differing numbers of N-donor units within a ligand strand containing a phenyl spacer results in a pentanuclear head-to-tail circular helicate, whereas reaction of two different ligands results in a heteroleptic pentanuclear circular helicate (see picture; green: Cu, red and blue: ligands). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6655 / 6658

页数：4

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