Block copolymer-templated mesoporous oxides

被引:438
作者
Soler-Illia, GJDA
Crepaldi, EL
Grosso, D
Sanchez, C
机构
[1] Univ Paris 06, CNRS UMR 7574, Lab Chim Mat Condensee, F-75252 Paris 05, France
[2] Comis Nacl Energia Atom, Ctr Atom Constituyentes, Unidad Actividad Quim, RA-1650 San Martin, Buenos Aires, Argentina
[3] Rhodia Brasil Ltd, CPP, Fisicoquim, BR-13140000 Paulinia, SP, Brazil
关键词
polymer; mesoporous materials; surfactant; block copolymer; SBA-15;
D O I
10.1016/S1359-0294(03)00002-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Block copolymers (BC) are indeed suitable and versatile templates for the creation of mesostructured and mesoporous materials. Great advances have been achieved in the last 3 years. Nowadays, it is possible to obtain highly controlled large-pore and highly stable mesostructured and mesoporous materials (silica, non-silica oxides, carbons,...) shaped as powders, films, monoliths or aerosols. This paper reviews mainly the synthesis of BC-templated mesostructured oxides, stressing in the physical, chemical and processing parameters, which have to be thoroughly controlled to reproducibly obtain mesoporous materials. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:109 / 126
页数:18
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