Melting behavior of levitated Y2O3

被引:26
作者
Hennet, L
Thiaudière, D
Landron, C
Melin, P
Price, DL
Coutures, JP
Bérar, JF
Saboungi, ML
机构
[1] CRMHT, F-45071 Orleans 2, France
[2] IMP, Rambla Thermodynam, F-66100 Perpignan, France
[3] LCG, F-38042 Grenoble 9, France
[4] CRMD, F-45071 Orleans 2, France
关键词
D O I
10.1063/1.1621090
中图分类号
O59 [应用物理学];
学科分类号
摘要
The yttrium environment in liquid Y2O3 at 2770 K has been measured with anomalous x-ray scattering, aerodynamic levitation, and laser heating. The Y-O coordination of 6-7 and the Y-Y coordination of around 12 imply that the close packing of the high-temperature (H-type) solid phase is preserved on melting, in contrast to the large structural changes exhibited by Al2O3. The unusually sharp main diffraction peak implies a high degree of chemical order and mirrors the diffraction pattern of the H-type phase. (C) 2003 American Institute of Physics.
引用
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页码:3305 / 3307
页数:3
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