Very high sensitivity CW-cavity ring down spectroscopy:: Application to the a 1Δg(0)-X 3Σ-g(1) O2 band near 1.58 μm

被引：27

作者：

Kassi, S

Romanini, D

Campargue, A

Bussery-Honvault, B

机构：

[1] Univ Grenoble 1, CNRS, UMR 5588, Spectrometrie Phys Lab, F-38402 St Martin Dheres, France

[2] Univ Rennes 1, CNRS, UMR 6627, Lab Phys Atomes Lasers Mol & Surfaces, F-35042 Rennes, France

来源：

CHEMICAL PHYSICS LETTERS | 2005年 / 409卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2005.05.033

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A few absorption lines of the (Q)Q branch of the a(1)Delta(g)-(0)-X(3)Sigma(g)(-) (1) hot band of pure O-2 have been detected near 1.58 mu m by CW-cavity ring down spectroscopy based on a fibred DFB laser. A sensitivity of the order of 2 x 10(-11) cm(-1) has been achieved by averaging a large number of spectra, allowing for the measurement of line intensities as weak as 5 x 10(-31) cm/molecule. The integrated band intensity is estimated to be S-01 = 4.5(7) x 10(-29) cm/molecule which differs by a factor of about 6 from the value provided by the HITRAN database. Our intensity value is supported by a significantly better agreement with the value deduced from the intensity of the a(1)Delta(g)(0)-X(3)Sigma g(-)(0) cold band and the respective Franck-Condon factors. (c) 2005 Elsevier B.V.. All rights reserved.

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页码：281 / 287

页数：7

相关论文

共 17 条

[1] Cold collisions of ground-state calcium atoms in a laser field: A theoretical study [J].

Bussery-Honvault, B ;

Launay, JM ;

Moszynski, R .

PHYSICAL REVIEW A, 2003, 68 (03) :14

[2] Determination of differential cross sections for electron-impact excitation of electronic states of molecular oxygen [J].

Campbell, L ;

Green, MA ;

Brunger, MJ ;

Teubner, PJO ;

Cartwright, DC .

PHYSICAL REVIEW A, 2000, 61 (02) :7

[3] High sensitivity cw-cavity ringdown and Fourier transform absorption spectroscopies of 13CO2 [J].

Ding, Y ;

Macko, P ;

Romanini, D ;

Perevalov, VI ;

Tashkun, SA ;

Teffo, JL ;

Hu, SM ;

Campargue, A .

JOURNAL OF MOLECULAR SPECTROSCOPY, 2004, 226 (02) :146-160

[4] Improved spectral parameters for the three most abundant isotopomers of the oxygen molecule [J].

Gamache, RR ;

Goldman, A ;

Rothman, LS .

JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 1998, 59 (3-5) :495-509

[5] Einstein A coefficient, integrated band intensity, and population factors:: application to the a1Δg-Χ3Σg-(0,0) O2 band [J].

Gamache, RR ;

Goldman, A .

JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2001, 69 (04) :389-401

[6] 1DELTA-G-3SIGMA-G-O-2 INFRARED EMISSION BAND IN THE TWILIGHT AIRGLOW SPECTRUM [J].

JONES, AV ;

HARRISON, AW .

JOURNAL OF ATMOSPHERIC AND TERRESTRIAL PHYSICS, 1958, 13 (1-2) :45-60

[7] CALCULATION OF SPIN-FORBIDDEN RADIATIVE TRANSITIONS USING CORRELATED WAVEFUNCTIONS - LIFETIMES OF B1-SIGMA-+, A1-DELTA-STATES IN O2, S2 AND SO [J].

KLOTZ, R ;

MARIAN, CM ;

PEYERIMHOFF, SD ;

HESS, BA ;

BUENKER, RJ .

CHEMICAL PHYSICS, 1984, 89 (02) :223-236

[8]

Krupenie, 1972, J PHYS CHEM REF DATA, V1, P423, DOI DOI 10.1063/1.3253101

[9] High sensitivity CW-cavity ring down spectroscopy of water in the region of the 1.5 μm atmospheric window [J].

Macko, P ;

Romanini, D ;

Mikhailenko, SN ;

Naumenko, OV ;

Kassi, S ;

Jenouvrier, A ;

Tyuterev, VG ;

Campargue, A .

JOURNAL OF MOLECULAR SPECTROSCOPY, 2004, 227 (01) :90-108

[10] High-sensitivity CW-cavity ringdown spectroscopy of 12CO2 near 1.5 μm [J].

Majcherova, Z ;

Macko, P ;

Romanini, D ;

Perevalov, VI ;

Tashkun, SA ;

Teffo, JL ;

Campargue, A .

JOURNAL OF MOLECULAR SPECTROSCOPY, 2005, 230 (01) :1-21