Contamination of animal feed and food from animal origin with mineral oil hydrocarbons

被引:48
作者
Grob, K [1 ]
Vass, M [1 ]
Biedermann, M [1 ]
Neukom, P [1 ]
机构
[1] Off Food Control Author Canton Zurich, CH-8030 Zurich, Switzerland
来源
FOOD ADDITIVES AND CONTAMINANTS PART A-CHEMISTRY ANALYSIS CONTROL EXPOSURE & RISK ASSESSMENT | 2001年 / 18卷 / 01期
关键词
animal feed; contamination; waste oils; hydrocarbons; motor oil; eggs; animal body fat;
D O I
10.1080/02652030010003503
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Oils and fats used for the production of animal feed can become contaminated with mineral oil material originating from gas oils (C18-C35) or synthetic oils (poly-alpha olefins, C-25 to beyond C-45). An important cause is assumed to be the discharge of waste oils, such as motor oil and hydraulic oils. Mineral oil material was analysed by on-line LC-GC-FID directly in the fat or in a raw extract from animal feed or foodstuffs. In Switzerland in summer/autumn 1999 concentrations in oils and fats for feed production were often found to be between 100 and 1000 mg/kg. In the feeds, the average concentration was around 100 mg/kg with values ranging up to a maximum of 1000 mg/kg; few samples were free of contamination. In animal body fat, the average concentration determined in summer 1999 was 25 mg/kg, with a maximum of 150 mg/kg, although in samples from December 1999, contamination was substantially lower. In the fat phase of eggs, the average concentration was 30 mg/kg, with a maximum of 80 mg/kg. Paraffin oil is used for feed production, which may account for part of the contamination problem (e.g. eggs).
引用
收藏
页码:1 / 10
页数:10
相关论文
共 9 条
[1]  
[Anonymous], 1991, ON LINE COUPLED LC G
[2]  
BARTZ W, 1994, ADDITIVE SCHMIERSTOF
[3]  
BARTZ WJ, 1988, TRIBOLOGIE SCHMIERST
[4]   Determination of zinc O,O'-dialkyl dithiophosphate lubricant additives via the corresponding methyl and p-nitrobenzylic ester derivatives using GC-MS, GC-NPD and HPLC-MS [J].
Becker, R ;
Hoffmann, W ;
Knorr, A ;
Walther, W ;
Lehmann, A .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1997, 357 (06) :688-694
[5]  
GROB K, 1991, HRC-J HIGH RES CHROM, V14, P373
[6]   ONLINE LC-GC TRANSFER VIA A HOT VAPORIZING CHAMBER AND VAPOR DISCHARGE BY OVERFLOW - INCREASED SENSITIVITY FOR THE DETERMINATION OF MINERAL-OIL IN FOODS [J].
GROB, K ;
BRONZ, M .
JOURNAL OF MICROCOLUMN SEPARATIONS, 1995, 7 (04) :421-427
[7]   Efficiency through combining high-performance liquid chromatography and high resolution gas chromatography: progress 1995-1999 [J].
Grob, K .
JOURNAL OF CHROMATOGRAPHY A, 2000, 892 (1-2) :407-420
[8]   Separation of zinc dialkyldithiophosphates in lubricating oil additives by normal-phase high-performance liquid chromatography [J].
Lambropoulos, N ;
Cardwell, TJ ;
Caridi, D ;
Marriott, PJ .
JOURNAL OF CHROMATOGRAPHY A, 1996, 749 (1-2) :87-94
[9]  
*SCI COMM FOOD EUR, 1995, OP MIN SYNTH HYDR