Solid-state reshaping of crystals:: Flash increase in porosity of zirconium phosphate-hypophosphite that contains polyethylenoxa diphosphonate pillars

被引：24

作者：

Brunet, E ^{[1
]}

de la Mata, MJ ^{[1
]}

Juanes, O ^{[1
]}

Rodríguez-Ubis, JC ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Dept Quim Organ, Fac Ciencias C I, E-28049 Madrid, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 05期

关键词：

crystal engineering; layered compounds; supramolecular chemistry; topochemistry; zirconium;

D O I：

10.1002/anie.200352711

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Shape shifting: A novel pillared, solid organic-norganic phase is prepared by stepwise double topotactic exchange of γ-zirconium phosphate with pentaethylenglycol-derived diphosphonic acid and hypophosphite. The interlayer distance of the title material sharply increases when treated with methylamine. This enormous sensitivity of microcrystalline porosity towards intercalation of small molecules has no precedent.

引用

页码：619 / 621

页数：3

共 45 条

[1]

ALBERTI, 1996, COMPREHENSIVE SUPRAM, V7, pCH5

[2] PREPARATION AND SOME PROPERTIES OF ZR PHOSPHATE HYPOPHOSPHITE AND ZR PHOSPHATE DIMETHYLPHOSPHINATE WITH GAMMA-LAYERED STRUCTURE [J].

ALBERTI, G ;

CASCIOLA, M ;

BISWAS, RK .

INORGANICA CHIMICA ACTA, 1992, 201 (02) :207-212

[3]

Alberti G, 1999, ANGEW CHEM INT EDIT, V38, P3351, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3351::AID-ANIE3351>3.0.CO

[4]

2-V

[5]

Alberti G., 1999, ANGEW CHEM, V111, P3548

[6]

[Anonymous], HDB NANOSTRUCTURED M

[7]

Atwood J. L., 1996, COMPREHENSIVE SUPRAM, V11

[8] SYNTHESIS OF O-ALPHA-L-FUCOPYRANOSYL-(1-]3)-O-BETA-D-GALACTOPYRANOSYL-(1-]4)-D-GLUCOSE (3'-O-ALPHA-L-FUCOPYRANOSYLLACTOSE), AND AN IMPROVED ROUTE TO ITS BETA-(1''-]3')-LINKED ISOMER [J].

BAER, HH ;

ABBAS, SA .

CARBOHYDRATE RESEARCH, 1980, 84 (01) :53-60

[9]

BLANCMUESSER M, 1976, TETRAHEDRON LETT, P4307

[10] STEREOSELECTIVE SYNTHESIS OF 1-THIOGLYCOSIDES [J].

BLANCMUESSER, M ;

DEFAYE, J ;

DRIGUEZ, H .

CARBOHYDRATE RESEARCH, 1978, 67 (02) :305-328

← 1 2 3 4 5 →