Beyond Fe-only hydrogenases:: N-functionalized 2-aza-1,3-dithiolates Fe2[(SCH2)2NR](CO)x (x=5,6)

被引：155

作者：

Lawrence, JD ^{[1
]}

Li, HX ^{[1
]}

Rauchfuss, TB ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 16期

关键词：

D O I：

10.1039/b104195a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Primary amines undergo chloromethylation with CH2O/SOCl2 to give RN(CH2Cl)(2), which in turn react with Li-2[Fe2S2(CO)(6)] to give Fe-2[(SCH2)(2)NR](CO)(6); in the case of R = CH2CH=CH2 and CH2CH2SMe, Me3NO-induced decarbonylation afforded pentacarbonyl derivatives wherein the pendant functionality is coordinated to Fe.

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页码：1482 / 1483

页数：2

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