Interlinked molecular squares with [Cu(2,2′-bipy)]2+ corners generating a three-dimensional network of unprecedented topological type

被引：47

作者：

Carlucci, L

Ciani, G

Proserpio, DM

Rizzato, S

机构：

[1] CNR, Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

[2] Ctr CNR, I-20133 Milan, Italy

[3] Univ Insubria, Dipartimento Biol Strutturale & Funz, I-21100 Varese, Italy

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 13期

关键词：

D O I：

10.1039/b103736f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A noteworthy three-dimensional framework, obtained by reacting the preformed molecular corner [Cu(2,2'-bipy)](2+) (with BF4- counter ions) and 1,2-bis(4-pyridyl)ethane (bpetha) in the presence of chlorides, contains molecular square units [Cu(2,2'-bipy)(bpetha)](4) that are linked via chloride bridges into a triconnected architecture of unprecedented topology.

引用

页码：1198 / 1199

页数：2

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