Structures of Mn(II) thiocyanate co-ordination polymers from flexible bipyridyl ligands

被引：32

作者：

Plater, MJ ^{[1
]}

Foreman, MRS ^{[1
]}

Howie, RA ^{[1
]}

Skakle, JMS ^{[1
]}

机构：

[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland

来源：

INORGANICA CHIMICA ACTA | 2001年 / 318卷 / 1-2期

关键词：

crystal structures; coordination polymer complexes; manganese complexes; thiocyanate complexes;

D O I：

10.1016/S0020-1693(01)00398-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystallisation of flexible bipyridyl ligands with MnCl2. 4H(2)O and KSCN gives co-ordination polymers of composition [Mn(NCS)(2)(H2O)(2)(Py2C2H4)](Py2C2H4)(2)(H2O)(2) (1) (Py2C2H4 = 1,2-bis(4-pyridyl)ethane), [Mn-2(NCS)(4)(Py2C3H6)(4)](n) (2) (Py2C3H6 = 1,3-bis(4-pyridyl)propane) and [Mn(NCS)(2)(CH3CH2OH)(2)(Py2C6H12)](n) (3) (Py2C6H12 = 1,6-bis(4-pyridyl)hexane). The structures were solved by single crystal structure determinations. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：175 / 180

页数：6

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