Complex molecular architecture polymers via RAFT

被引:63
作者
Barner, L [1 ]
Barner-Kowollik, C [1 ]
Davis, TP [1 ]
Stenzel, MH [1 ]
机构
[1] Univ New S Wales, Sch Chem Engn & Ind Chem, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia
关键词
D O I
10.1071/CH03232
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of star and hydrogel polymers mediated by reversible addition-fragmentation chain-transfer (RAFT) polymerization was reported. The RAFT technique generates polymers with RAFT end groups, opening the possibility to restart the polymerization process. RAFT polymerization was therefore a very versatile route for the synthesis of star, comb, or block copolymers with good control over molecular weight.
引用
收藏
页码:19 / 24
页数:6
相关论文
共 34 条
[1]   Reversible addition-fragmentation chain-transfer graft polymerization of styrene: Solid phases for organic and peptide synthesis [J].
Barner, L ;
Zwaneveld, N ;
Perera, S ;
Pham, Y ;
Davis, TP .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (23) :4180-4192
[2]   Modeling the reversible addition-fragmentation chain transfer process in cumyl dithiobenzoate-mediated styrene homopolymerizations: Assessing rate coefficients for the addition-fragmentation equilibrium [J].
Barner-Kowollik, C ;
Quinn, JF ;
Morsley, DR ;
Davis, TP .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2001, 39 (09) :1353-1365
[3]   Nano- and micro-engineering of ordered porous blue-light-emitting films by templating well-defined organic polymers around condensing water droplets [J].
Barner-Kowollik, C ;
Dalton, H ;
Davis, TP ;
Stenzel, MH .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (31) :3664-3668
[4]   Kinetic investigations of reversible addition fragmentation chain transfer polymerizations: Cumyl phenyldithioacetate mediated homopolymerizations of styrene and methyl methacrylate [J].
Barner-Kowollik, C ;
Quinn, JF ;
Nguyen, TLU ;
Heuts, JPA ;
Davis, TP .
MACROMOLECULES, 2001, 34 (22) :7849-7857
[5]   Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process [J].
Chiefari, J ;
Chong, YK ;
Ercole, F ;
Krstina, J ;
Jeffery, J ;
Le, TPT ;
Mayadunne, RTA ;
Meijs, GF ;
Moad, CL ;
Moad, G ;
Rizzardo, E ;
Thang, SH .
MACROMOLECULES, 1998, 31 (16) :5559-5562
[6]   A more versatile route to block copolymers and other polymers of complex architecture by living radical polymerization: The RAFT process [J].
Chong, YK ;
Le, TPT ;
Moad, G ;
Rizzardo, E ;
Thang, SH .
MACROMOLECULES, 1999, 32 (06) :2071-2074
[7]  
Coote ML, 1998, J MACROMOL SCI R M C, VC38, P567
[8]   Sulfobetaine-containing diblock and triblock copolymers via reversible addition-fragmentation chain transfer polymerization in aqueous media [J].
Donovan, MS ;
Lowe, AB ;
Sanford, TA ;
McCormick, CL .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (09) :1262-1281
[9]   STRUCTURES AND COMPOSITIONS OF COPOLYMERS [J].
HARWOOD, HJ .
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1987, 10 :331-354
[10]   New polymer synthesis by nitroxide mediated living radical polymerizations [J].
Hawker, CJ ;
Bosman, AW ;
Harth, E .
CHEMICAL REVIEWS, 2001, 101 (12) :3661-3688