(Diethylenetriamine)(imidazole)(thiocyanato)copper(II) perchlorate

被引：6

作者：

Hu, HM ^{[1
]}

Sun, HS ^{[1
]}

Chen, XH ^{[1
]}

Zhao, Q ^{[1
]}

Pan, Y ^{[1
]}

Huang, XY ^{[1
]}

You, XZ ^{[1
]}

机构：

[1] STATE KEY LAB STRUCT CHEM,FUZHOU 350002,PEOPLES R CHINA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270196013893

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Cu atom in the title complex, [N-(2-amino-ethyl-N)-1,2-ethylenediamine-N,N'](imidazole-N-3)(thiocyanato-N)copper(II) perchlorate, [Cu(NCS)(C4H13N3)-(C3H4N2)]ClO4, is coordinated in a trigonal bipyramidal arrangement by two primary N atoms of N-(2-amino-ethyl)-1,2-ethylenediamine (diethylenetriamine) and one N atom of thiocyanate in equatorial positions, and by the 'pyridine' N atom of imidazole and one secondary N atom of diethylenetriamine in axial positions. The Cu-N(imidazole) and Cu-N(thiocyanate) bond lengths are 1.978(3) and 2.245 (4) Angstrom, respectively.

引用

页码：276 / 278

页数：3

共 13 条

[1] MAGNETIC, ELECTRON-SPIN-RESONANCE, ELECTROCHEMICAL, AND POTENTIOMETRIC TITRATION STUDIES OF THE IMIDAZOLATE-BRIDGED DICOPPER(II) ION IN A BINUCLEATING MACROCYCLE [J].