Synthesis, Radical Scavenging Activity, Protection during Storage, and Frying by Novel Antioxidants

被引:19
作者
Catel, Yohann [1 ]
Aladedunye, Felix [1 ]
Przybylski, Roman [1 ]
机构
[1] Univ Lethbridge, Dept Chem & Biochem, Lethbridge, AB T1K 3M4, Canada
关键词
Antioxidant; synthesis; frying; phenolics; radical scavenging activity; trolox; storage stability; frying performance; GALLIC ACID; FOOD LIPIDS; ATHEROSCLEROSIS; DERIVATIVES; OXIDATION; ANALOGS; TOCOPHEROLS; DISEASE; TESTS; CELLS;
D O I
10.1021/jf102287h
中图分类号
S [农业科学];
学科分类号
082806 [农业信息与电气工程];
摘要
Novel antioxidants, derivatives of trolox, and selected phenolic acids have been prepared in good yields and fully characterized by (1)H NMR, (13)C NMR, and MS. Their antioxidant activities have been assessed by DPPH and ORAC assays, and during frying and accelerated storage tests. Novel phenolic compounds exhibited higher radical scavenging activities than both trolox and alpha-tocopherol. Trolox hydroxybenzoate showed a significantly higher protection than alpha-tocopherol under storage conditions. All new antioxidants performed better than alpha-tocopherol under frying conditions. Moreover, their outstanding thermal stability makes them more valuable than alpha-tocopherol for frying applications.
引用
收藏
页码:11081 / 11089
页数:9
相关论文
共 41 条
[1]
Relationships between Free Radical Scavenging and Antioxidant Activity in Foods [J].
Alamed, Jean ;
Chaiyasit, Wilailuk ;
McClements, D. Julian ;
Decker, Eric A. .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2009, 57 (07) :2969-2976
[2]
[Anonymous], ADV OPTOELECTRONICS, DOI DOI 10.1155/2007/35383
[3]
[Anonymous], 1997, AOCS Official Method Cd 8-53: Peroxide Value - Acetic Acid-Chloroform Method, Re-approved 1997, V4th
[4]
*AOAC INC, 1990, OFF METH AN ASS OFF
[5]
ARNOTT EA, 2008, Patent No. 200805322
[6]
EFFICACY OF THE ANTI-OXIDANT BHA AND BHT IN PALM OLEIN DURING HEATING AND FRYING [J].
AUGUSTIN, MA ;
BERRY, SK .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1983, 60 (08) :1520-1523
[7]
The free radical theory of aging matures [J].
Beckman, KB ;
Ames, BN .
PHYSIOLOGICAL REVIEWS, 1998, 78 (02) :547-581
[8]
THE DATA SUPPORT A ROLE FOR ANTIOXIDANTS IN REDUCING CANCER RISK [J].
BLOCK, G .
NUTRITION REVIEWS, 1992, 50 (07) :207-213
[9]
How to standardize the multiplicity of methods to evaluate natural antioxidants [J].
Frankel, Edwin N. ;
Finley, John W. .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2008, 56 (13) :4901-4908
[10]
2 TYPES OF ANTIMUTAGENIC EFFECTS OF GALLIC AND TANNIC ACIDS TOWARDS N-NITROSO-COMPOUNDS-INDUCED MUTAGENICITY IN THE AMES SALMONELLA ASSAY [J].
GICHNER, T ;
POSPISIL, F ;
VELEMINSKY, J ;
VOLKEOVA, V ;
VOLKE, J .
FOLIA MICROBIOLOGICA, 1987, 32 (01) :55-62