Upconversion photoluminescence in poly(ladder-type-pentaphenylene) doped with metal (II)-octaethyl porphyrins -: art. no. 061904

被引:79
作者
Baluschev, S
Keivanidis, PE
Wegner, G
Jacob, J
Grimsdale, AC
Müllen, K
Miteva, T
Yasuda, A
Nelles, G
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
[2] Sony Deutschland, Mat Sci Lab, D-70327 Stuttgart, Germany
关键词
D O I
10.1063/1.1857073
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report on the optimization of the upconversion photoluminescence in films of conjugated polymers doped with platinum porphyrin. The upconversion emission was observed to take place at pump intensities as low as 0.5 kW/cm(2). Comparison between the photoluminescence integral intensity of polyfluorene and ladder-type pentaphenylene polymer shows a five-fold increase of the efficiency of the upconversion process for the latter. The higher upconversion efficiency can be partially attributed to the reduced reabsorption of the photoluminescence in the case of the ladder-type pentaphenylene matrix. (C) 2005 American Institute of Physics.
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页码:1 / 3
页数:3
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