Cycloaddition of nitrile oxides to aza-analogues of phenanthrene

被引：9

作者：

Corsaro, A ^{[1
]}

Librando, V ^{[1
]}

Chiacchio, U ^{[1
]}

Pistarà, V ^{[1
]}

Rescifina, A ^{[1
]}

机构：

[1] Univ Catania, Dipartimento Sci Chim, I-95125 Catania, Italy

来源：

TETRAHEDRON | 1998年 / 54卷 / 31期

关键词：

D O I：

10.1016/S0040-4020(98)00556-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Mesitonitrile oxide, but not benzonitrile oxide, adds to ate-analogues of phenanthrene to give low yields of monocycloadducts. Only phenanthridine reacts with the two nitrile oxides affording phenanthridinone. 4,7-phenanthroline also gives some other minor products among which the bisadduct to a pyridine ring was isolated. The reactivity of aza-analogues under examination is discussed in terms of FMO approximation. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：9187 / 9194

页数：8

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