The critical hydration reactions of NO+ and NO2+

被引:27
作者
Angel, L [1 ]
Stace, AJ [1 ]
机构
[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England
关键词
D O I
10.1063/1.476744
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The reactions of NO+ and NO2+ with water are considered to make an important contribution to the formation of proton hydrates in the upper atmosphere. There have been several-recent studies of the; relevant reactions, with the result that discrepancies have arisen in each case over the critical number of water molecules required to promote the appearance of a proton hydrate, Presented here are new results based on the collision-induced reactions of NO+.(H2O)(n) and NO2+.(H2O)(n) cluster ions, which we believe clarify the situation. (C) 1998 American Institute of Physics.
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收藏
页码:1713 / 1715
页数:3
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