Topotactic synthesis of α-zirconium phenylphosphonate from α-zirconium phosphate

被引：17

作者：

Hix, GB ^{[1
]}

Kitchin, SJ ^{[1
]}

Harris, KDM ^{[1
]}

机构：

[1] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 14期

关键词：

D O I：

10.1039/a802673d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

alpha-Zirconium phenylphosphonate has been synthesised by a reaction between a-zirconium phosphate and molten phenylphosphonic acid. The reaction produces a physical mixture of the 'pure' phases of alpha-zirconium phenylphosphonate and a-zirconium phosphate, with the ratio dependent on the ratio of phenylphosphonic acid to alpha-zirconium phosphate in the synthesis mixture. Detailed characterization of the reaction products has been carried out by powder X-ray diffraction, high-resolution solid-state P-31 NMR spectroscopy, thermogravimetric analysis and FT-IR spectroscopy, and by considering experiments involving the selective intercalation of n-butylamine.

引用

页码：2315 / 2319

页数：5

共 28 条

[1] Layered metal(IV) phosphonates, a large class of inorgano-organic proton conductors [J].

Alberti, G ;

Casciola, M .

SOLID STATE IONICS, 1997, 97 (1-4) :177-186

[2] PROTONIC CONDUCTIVITY OF LAYERED ZIRCONIUM PHOSPHONATES CONTAINING -SO3H GROUPS .1. PREPARATION AND CHARACTERIZATION OF A MIXED ZIRCONIUM PHOSPHONATE OF COMPOSITION ZR(O3PR)0.73(O3PR')1.27.NH2O, WITH R = -C6H4-SO3H AND R' = -CH2-OH [J].

ALBERTI, G ;

CASCIOLA, M ;

COSTANTINO, U ;

PERAIO, A ;

MONTONERI, E .

SOLID STATE IONICS, 1992, 50 (3-4) :315-322

[3] PROTONIC CONDUCTIVITY OF LAYERED ZIRCONIUM PHOSPHONATES CONTAINING-SO3H GROUPS .2. AC CONDUCTIVITY OF ZIRCONIUM ALKYL SULFOPHENYL PHOSPHONATES IN THE RANGE 100-200-DEGREES-C, IN THE PRESENCE OR ABSENCE OF WATER-VAPOR [J].

ALBERTI, G ;

CASCIOLA, M ;

PALOMBARI, R ;

PERAIO, A .

SOLID STATE IONICS, 1992, 58 (3-4) :339-344

[4] RECENT PROGRESS IN THE INTERCALATION CHEMISTRY OF LAYERED ALPHA-ZIRCONIUM PHOSPHATE AND ITS DERIVATIVES, AND FUTURE PERSPECTIVES FOR THEIR USE IN CATALYSIS [J].

ALBERTI, G ;

CONSTANTINO, U .

JOURNAL OF MOLECULAR CATALYSIS, 1984, 27 (1-2) :235-250

[5] CRYSTALLINE ZR(R-PO3)2 AND ZR(R-OPO3)2 COMPOUNDS (R=ORGANIC RADICAL) - NEW CLASS OF MATERIALS HAVING LAYERED STRUCTURE OF ZIRCONIUM-PHOSPHATE TYPE [J].

ALBERTI, G ;

COSTANTINO, U ;

ALLULLI, S ;

TOMASSINI, N .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1978, 40 (06) :1113-1117

[6] Layered and pillared metal(IV) phosphates and phosphonates [J].

Alberti, G ;

Casciola, M ;

Costantino, U ;

Vivani, R .

ADVANCED MATERIALS, 1996, 8 (04) :291-303

[7] SOL-GEL SYNTHESIS OF ZR(HPO4)2.H2O [J].

BENHAMZA, H ;

BARBOUX, P ;

BOUHAOUSS, A ;

JOSIEN, FA ;

LIVAGE, J .

JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (04) :681-684

[8] ZIRCONIUM 2-AMINO ETHYL PHOSPHONATE - PREPARATION, CHARACTERIZATION AND PRELIMINARY-STUDY OF ITS ELECTRICAL-CONDUCTIVITY AND INTERCALATION PROPERTIES [J].

CASCIOLA, M ;

COSTANTINO, U ;

PERAIO, A ;

REGA, T .

SOLID STATE IONICS, 1995, 77 :229-233

[9] SOLID-STATE NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPIC STUDY OF GAMMA-ZIRCONIUM PHOSPHATE [J].

CLAYDEN, NJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (08) :1877-1881

[10] NEW CRYSTALLINE PHASES OF ZIRCONIUM PHOSPHATE POSSESSING ION-EXCHANGE PROPERTIES [J].

CLEARFIELD, A ;

BLESSING, RH ;

STYNES, JA .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1968, 30 (08) :2249-+

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