Polymerization of lactams .89. Magnesium caprolactamates as initiators of epsilon-caprolactam polymerization

被引：8

作者：

Novakova, V ^{[1
]}

Sachova, M ^{[1
]}

Brozek, J ^{[1
]}

Bernat, P ^{[1
]}

Roda, J ^{[1
]}

机构：

[1] INST CHEM TECHNOL,DEPT POLYMERS,CR-16628 PRAGUE,CZECH REPUBLIC

来源：

MACROMOLECULAR SYMPOSIA | 1996年 / 102卷

关键词：

D O I：

10.1002/masy.19961020116

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The anionic polymerization of epsilon-caprolactam initiated with magnesium initiators was studied in the interval 180-250 degrees C. epsilon-Caprolactam magnesium bromide was much more active than magnesium di(epsilon-caprolacramate) and the activity of both depended on the way of their preparation. The polymerizations obey the zero order kinetics with respect to the monomer.

引用

页码：115 / 122

页数：8

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