Investigation of the initiation behavior of a dendritic 12-arm initiator in atom transfer radical polymerization

被引：67

作者：

Heise, A

Diamanti, S

Hedrick, JL

Frank, CW

Miller, RD

机构：

[1] IBM Corp, Res Ctr, San Jose, CA 95120 USA

[2] Stanford Univ, Dept Chem Engn, Stanford, CA 95305 USA

来源：

MACROMOLECULES | 2001年 / 34卷 / 11期

关键词：

D O I：

10.1021/ma001508p

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The initiation behavior of a dendritic 12-arm atom transfer radical polymerization (ATRP) initiator was studied. The number of initiated arms were found to increase with an increase in molecular weight of the arms. The minimum molecular weight to ensure complete initiation was found to depend on the reaction conditions.

引用

收藏

页码：3798 / 3801

页数：4

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