Four-layer complexation model for ion adsorption at electrolyte/oxide interface: Interrelations of model parameters

被引：29

作者：

Charmas, R

Piasecki, W

机构：

[1] Department of Theoretical Chemistry, Faculty of Chemistry, Maria Curie Skłodowska Univ., 20-031 Lublin

来源：

LANGMUIR | 1996年 / 12卷 / 22期

关键词：

D O I：

10.1021/la960234p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A profound theoretical analysis is presented of the four layer complexation model assuming that adsorbed anions and cations are located in two distinct layers, The theoretical relations between the intrinsic complexation constants. developed in our previous paper (Langmuir 1995, 22, 3199) are subjected to an exhaustive numerical analysis, along with the newly developed relation between PZC and IEP. That analysis shows that the dependence of the electrical capacitances in the system on the activity of the bulk electrolyte is of crucial importance for the behavior of these systems.

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页码：5458 / 5465

页数：8

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