Synthesis of bipyridine and biquinoline complexes of group 4 metallocenes

被引：8

作者：

Bishop, LA

Turner, MA

Kool, LB

机构：

[1] Boston Coll, Eugene F Merkert Chem Ctr, Dept Chem, Chestnut Hill, MA 02167 USA

[2] Gen Elect Superabras, Worthington, OH 43085 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 553卷 / 1-2期

关键词：

D O I：

10.1016/S0022-328X(97)00467-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes Cp2ML2, with M = Ti, Zr and Hf, and L-2 = bipyridyl, biquinoline and 4,4'-dimethyl-2,2'-bipyridyl, were prepared in excellent yields via magnesium reduction of the respective group 4 metallocene dichlorides in THF solution. H-1 NMR spectroscopy in benzene-d(6) indicates that this synthetic route affords Cp2Ti(bpy) as a diamagnetic product. (C) 1998 Elsevier Science S.A.

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页码：53 / 57

页数：5

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