Synthesis of conducting graft copolymers of 2-(N-pyrrolyl)ethylvinyl ether with pyrrole

被引:7
作者
Bengü, B
Toppare, L [1 ]
Kalaycioglu, E
机构
[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey
[2] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA
关键词
2-(N-pyrrolyl)-ethylvinyl ether; pyrrole; electrochemical polymerization; block copolymers;
D O I
10.1163/156855501744865
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
2-(N-pyrrolyl)ethylvinyl ether (2-NEVE) was synthesized from 2-chloroethylvinyl ether (2-CEVE) via a phase catalysis reaction. Cyclic voltammetric studies were carried out to check for the electroactivity of 2-NEVE. Poly(2-(N-pyrrolyl)ethylvinyl ether) [poly(2-NEVE)] was synthesized via chemical methods. Graft copolymers of pyrrole and 2-NEVE were synthesized by electrochemical methods. The chemical structures of 2-NEVE and poly(2-NEVE) were investigated by several spectroscopic methods. Graft copolymers were characterized by means of FTIR, scanning electron microscopy (SEM). differential scanning calorimetry (DSC), and thermal gravimetric analysis (TGA). The conductivities of the graft copolymers were measured via a four-probe technique.
引用
收藏
页码:53 / 65
页数:13
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