Enantioselective synthesis of thiosulfinates and of acyclic alkylidenemethylene sulfide sulfoxides

被引：21

作者：

Colonna, S

Pironti, V

Drabowicz, J

Brebion, F

Fensterbank, L

Malacria, M

机构：

[1] Fac Farm, Inst Chim Organ A Narchesini, I-20131 Milan, Italy

[2] Polish Acad Sci, Dept Heteroorgan Chem, PL-90363 Lodz, Poland

[3] Univ Paris 06, CNRS, UMR 7611, Chim Organ Lab, F-75252 Paris, France

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 2005卷 / 09期

关键词：

chiral dioxirane; thiosulfinate; asymmetric synthesis; bovine serum albumin; enantioselectivity;

D O I：

10.1002/ejoc.200400892

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantioselectivities up to 75% have been found in the catalytic mono-oxidation of di-tert-butyl disulfide and related compounds as well as of ketene-S,S-acetals with an in situ generated chiral dioxirane. The effect of solvents on the enantiomeric excess has also been examined. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).

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页码：1727 / 1730

页数：4

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