Synthesis and Photodynamics of 9-Mesitylacridinium Ion-Modified Gold Nanoclusters

被引：25

作者：

Fukuzumi, Shunichi ^{[1
]}

Hanazaki, Ryo ^{[1
]}

Kotani, Hiroaki ^{[1
]}

Ohkubo, Kei ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, Osaka 5650871, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 32期

关键词：

ELECTRON-TRANSFER STATE; 9-MESITYL-10-METHYLACRIDINIUM ION; CLUSTER MOLECULES; NANOPARTICLES; PORPHYRIN; ENERGY; IMPURITIES; COMPOSITE; CELLS; SNO2;

D O I：

10.1021/ja105314x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photoexcitation of gold nanoclusters covalently functionalized with 9-mesityl-10-methylacridinium ion (Mes-Acr(+)) resulted in the formation of the electron-transfer state (Mes(center dot+)-Acr(center dot)), which forms a pi-dimer radical cation with the neighboring Mes-Acr(+) via an intramolecular pi-pi a interaction.

引用

页码：11002 / 11003

页数：2

共 33 条

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