First synthesis of cationic [(η6-arene)Mn(CO)3] complexes substituted by resonance electron withdrawing groups

被引：22

作者：

Auffrant, A

Prim, D

Rose-Munch, F

Rose, E

Vaissermann, J

机构：

[1] Univ Paris 06, CNRS, UMR 7611, Lab Synth Organ & Organomet, F-75252 Paris 05, France

[2] Univ Paris 06, CNRS, ESA 7071, Lab Chim Inorgan & Mat Mol, F-75252 Paris 05, France

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 15期

关键词：

D O I：

10.1021/om010162j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An unprecedented class of cationic [(eta (6)-RCO-arene)Mn(CO)(3)] complexes bearing resonance electron withdrawing groups have been synthesized by a high-yield two-step methodology starting from the neutral (eta (5)-1-chlorocyclohexadienyl)Mn(CO)(3) complex, employing a facile and selective transition-metal-catalyzed carbonylation followed by rearomatization, Definitive spectroscopic details of the novel [(eta (6)-RCO-arene)Mn(CO)(3)](+) products are discussed, and in one case (R = PhO), the structure has been confirmed by X-ray crystallography.

引用

页码：3214 / 3216

页数：3

共 20 条

[1]

[Anonymous], 1995, Comprehensive Organometallic Chemistry II

[2]

ASTRUC D, 2000, CHIMIE ORGANOMETALLI, P87

[3] OXIDATIVE ADDITION OF CATIONIC (ETA(6)-CHLOROARENE)TRICARBONYLMANGANESE COMPOUNDS TO PALLADIUM(O) COMPLEXES - SYNTHESIS, CHARACTERIZATION AND REACTIVITY [J].