Conical intersections: The new conventional wisdom

被引:334
作者
Yarkony, DR [1 ]
机构
[1] Johns Hopkins Univ, Dept Chem, Baltimore, MD 21218 USA
关键词
D O I
10.1021/jp003731u
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
During the past decade the perception of conical intersections has changed. It is now appreciated that what was once viewed largely as a theoretical curiosity is an essential aspect of electronically nonadiabatic processes. Concomitantly, our understanding of this singular consequence of the Born-Oppenheimer separation of nuclear and electronic motion has grown enormously. In this work the theory of conical intersections is reviewed.
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收藏
页码:6277 / 6293
页数:17
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