Glow-discharge plasma-assisted design of cobalt catalysts for Fischer-Tropsch synthesis

被引：167

作者：

Chu, Wei ^{[1
]}

Wang, Li-Nan ^{[1
]}

Chernavskii, Petr A. ^{[3
]}

Khodakov, Andrei Y. ^{[2
]}

机构：

[1] Sichuan Univ, Dept Chem Engn, Chengdu 610065, Peoples R China

[2] USTL ENSCL EC Lille, Unite Catalyse & Chim Solide, F-59655 Villeneuve Dascq, France

[3] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 27期

关键词：

Fischer-Tropsch synthesis; heterogeneous catalysis; magnetic properties; plasma chemistry; supported catalysts;

D O I：

10.1002/anie.200800657

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Plasma pretreatment of cobalt Fischer-Tropsch catalysts through glow discharge decomposes cobalt nitrate at much lower temperatures than conventional calcination, and smaller superparamagnetic Co metal particles (<7 nm) are formed (see schematic representation). The Fischer-Tropsch reaction rates with these catalysts are higher than or comparable to those of their counterparts prepared by conventional calcination at 473 K. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5052 / 5055

页数：4

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