Nanostructured TiO2 films with 2 eV optical gaps

被引：139

作者：

Barborini, E

Conti, AM

Kholmanov, I

Piseri, P

Podestà, A

Milani, P

Cepek, C

Sakho, O

Macovez, R

Sancrotti, M

机构：

[1] Univ Milan, Dipartimento Fis, INFM, I-20133 Milan, Italy

[2] Univ Milan, CIMAINA, I-20133 Milan, Italy

[3] INFM, TASC, Lab Nazl, I-34012 Trieste, Italy

[4] Univ Cattolica Sacro Cuore, INFM, Dipartimento Matemat & Fis, I-25121 Brescia, Italy

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 15期

关键词：

D O I：

10.1002/adma.200401169

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanostructured TiO2 (ns-TiO2) films obtained by supersonic cluster beam deposition possess highly porous, defective structures, and allow efficient incorporation of carbon-containing molecules during thermal treatment. Carbothermal reduction modifies the electronic structure of the ns-TiO2, narrowing the optical gap to 2 eV. This is within the range of visible solar radiation (see Figure), allowing more efficient photoconversion.

引用

页码：1842 / +

页数：6

共 28 条

[1] Design and development of titanium oxide photocatalysts operating under visible and UV light irradiation.: The applications of metal ion-implantation techniques to semiconducting TiO2 and Ti/zeolite catalysts [J].