Post-synthesis functionalization of (meth)acrylate based monoliths via electron beam triggered graft polymerization

被引：19

作者：

Beier, Matthias J. ^{[1
]}

Knolle, Wolfgang ^{[1
]}

Prager-Duschke, Andrea ^{[1
]}

Buchmeiser, Michael R. ^{[1
,2
]}

机构：

[1] Leibniz Inst Oberflachenmodifizierung eV IOM, D-04138 Leipzig, Germany

[2] Univ Leipzig, Inst Tech Chem, D-04103 Leipzig, Germany

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2008年 / 29卷 / 11期

关键词：

catalysis; electron beam curing; graft copolymers; heteroatom-containing polymers;

D O I：

10.1002/marc.200800153

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Porous polymeric monoliths were prepared via electron beam triggered free radical polymerization of (meth)acrylates. Post-synthesis functionalization of these supports was accomplished via electron beam initiated free radical graft polymerization of methacryloyl-substituted NHC precursors. The grafted precursors were converted into the corresponding copper complexes. Cu-loadings were between 1.3 mg . g(-1) and 1.5 mg . g(-1). These supported catalysts were used in selected C = O hydrosilylation and cyanosilylation reactions using a continuous flow setup.

引用

页码：904 / 909

页数：6

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