N-heterocyclic carbenes from transition metal coordinated functional isocyanides of the type o-(CH2Y)C6H4NC (Y=OSiMe3, OH; N3; AsR3+)

被引:32
作者
Basato, M
Michelin, RA
Mozzon, M
Sgarbossa, P
Tassan, A
机构
[1] Univ Padua, Dipartimento Proc Chim Ingn, I-35131 Padua, Italy
[2] Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy
关键词
carbenes; NHC ligands; functional isocyanides; transition metal complexes;
D O I
10.1016/j.jorganchem.2005.07.021
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis, transition metal coordination and reactivity of the functional isocyanides o-(CH2Y)C6H4-N C (Y = OSiMe3, OH; N-3; AsR3+) to afford N-heterocyclic carbenes is shortly reviewed. (c) 2005 Elsevier B.V. All rights :reserved.
引用
收藏
页码:5414 / 5420
页数:7
相关论文
共 56 条
[1]  
AHN SY, 1991, J ORGANOMET CHEM, V418, P365, DOI 10.1016/0022-328X(91)80222-6
[2]  
Alvarez SG, 1997, SYNTHESIS-STUTTGART, P413
[3]   Looking for stable carbenes: The difficulty in starting anew [J].
Arduengo, AJ .
ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) :913-921
[4]   MODES OF REACTION OF 2-HYDROXYALKYL ISOCYANIDES AND 3-HYDROXYALKYL ISOCYANIDES WITH METAL-COMPOUNDS - OXAZOLIDINYLIDENE AND PERHYDROOXAZINYLIDENE COMPLEXES OF PALLADIUM, PLATINUM, AND GOLD [J].
BARTEL, K ;
FEHLHAMMER, WP .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1974, 13 (09) :599-600
[5]   The Staudinger reaction of platinum(II)- and palladium(II)-coordinated 2-(azidomethyl)phenyl isocyanide.: X-ray structure of trans-[PtCl{CN(H)C6H4-2-CH2N(H)} (PPh3)2][BF4] • CDCl3 • H2O [J].
Basato, M ;
Benetollo, F ;
Facchin, G ;
Michelin, RA ;
Mozzon, M ;
Pugliese, S ;
Sgarbossa, P ;
Sbovata, SM ;
Tassan, A .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (02) :454-462
[6]   Transition metal coordination and reactivity of 2-(azidomethyl)-, 2-(chloromethyl)- and 2-(iodomethyl)phenyl isocyanides [J].
Basato, M ;
Facchin, G ;
Michelin, RA ;
Mozzon, M ;
Pugliese, S ;
Sgarbossa, P ;
Tassan, A .
INORGANICA CHIMICA ACTA, 2003, 356 :349-356
[7]   REACTIONS OF PENTACARBONYL(TRICHLOROMETHYL ISOCYANIDE)CHROMIUM [J].
BECK, G ;
FEHLHAMMER, WP .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (10) :1344-1347
[8]   MECHANISMS OF NUCLEOPHILIC AND ELECTROPHILIC ATTACK ON CARBON BONDED PALLADIUM(II) AND PLATINUM(II) COMPLEXES [J].
BELLUCO, U ;
MICHELIN, RA ;
UGUAGLIATI, P .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 250 (01) :565-587
[9]   Stable carbenes [J].
Bourissou, D ;
Guerret, O ;
Gabbaï, FP ;
Bertrand, G .
CHEMICAL REVIEWS, 2000, 100 (01) :39-91
[10]   The reactions of stable nucleophilic carbenes with main group compounds [J].
Carmalt, CJ ;
Cowley, AH .
ADVANCES IN INORGANIC CHEMISTRY, VOL 50: MAIN GROUP CHEMISTRY, 2000, 50 :1-32