First uranium(IV) triflates

被引:29
作者
Berthet, JC [1 ]
Lance, M
Nierlich, M
Ephritikhine, M
机构
[1] CEA Saclay, CNRS, URA 331, Lab Chim Uranuim,Serv Chim Uranium, F-91191 Gif Sur Yvette, France
[2] CEA Saclay, CNRS, URA 331, Lab Cristallochim,Serv Chim Mol, F-91191 Gif Sur Yvette, France
关键词
D O I
10.1039/a801936c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The uranium(IV) triflates [U(Cp*)(2)(OTf)(2)], [U(Cp)(2)(OTf)(2)(py)], [U(Cp)(3)(OTf)], [U(cot)(OTf)(2)(py)] and [U(OTf)(4)(py)] have been synthesized by protonation of amide or alkyl precursors with pyridinium triflate; the crystal structures of [U(Cp*)(2)(OTf)(2)(OH2)] and [U(Cp)(3)(OTf)(CNBut)] have been determined.
引用
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页码:1373 / 1374
页数:2
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