Self-assembled dahlia-like cadmium hydrogen phosphate hydrate nanostructures as templates for cadmium hydroxyapatite hexagonal prisms

被引：6

作者：

Arami, Hamed ^{[1
]}

Mazloumi, Mahyar ^{[1
]}

Khalifehzadeh, Razieh ^{[1
]}

Lak, Aidin ^{[1
]}

Sadrnezhaad, S. K. ^{[1
]}

机构：

[1] Mat & Energy Res Ctr, Tehran, Iran

来源：

JOURNAL OF CRYSTAL GROWTH | 2007年 / 309卷 / 01期

关键词：

nanostructures; growth from solutions; cadmium compounds; nanomaterials;

D O I：

10.1016/j.jcrysgro.2007.08.021

中图分类号：

O7 [晶体学];

学科分类号：

0702 [物理学]; 070205 [凝聚态物理]; 0703 [化学]; 080501 [材料物理与化学];

摘要：

Cadmium hydroxyapatite (Cd-Hap, Cd-10(PO4)(6)(OH)(2)) and cadmium hydrogen phosphate hydrate (Cd5H2(PO4)(4)center dot 4H(2)O) nanostructures with average crystallite sizes of about 38 and 44 nm, respectively, were prepared through a simple chemical process. The formation mechanism and characteristics of the Cd5H2(PO4)(4)center dot 4H(2)O precipitates prior to the hydrothermal process and Cd-Hap during the hydrothermal treatment were investigated with XRD, SEM, TEM and BET analyses. It was found that self-assembled dahlia-like Cd5H2(PO4)(4)center dot 4H(2)O nanostructure precipitates were formed due to interlace of preliminary nanosheets prior to the hydrothermal process, while nanostructure Cd-Hap hexagonal prisms were prepared after 15 h of hydrothermal treatment. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：37 / 42

页数：6

共 16 条

[1]

Biomineralization - Naturally aligned nanocrystals [J].