Solid-state solvolysis induced via charge-transfer complexation by solid-phase grinding followed by contact with solvent vapor

被引：17

作者：

Tanaka, M ^{[1
]}

Kobayashi, K ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Arts & Sci, Dept Chem, Meguro Ku, Tokyo 1538902, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 18期

关键词：

D O I：

10.1039/a803496f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

When 9-thienothienylfluoren-9-ol derivatives were ground together with DDQ then exposed to methanol vapor, solvolysis occurred to yield 9-methoxyfluorenes via the generation of a radical cation by solid-state single-electron transfer.

引用

页码：1965 / 1966

页数：2

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