Synthesis and photovoltaic performance of new diketopyrrolopyrrole (DPP) dyes for dye-sensitized solar cells

被引：50

作者：

Guo, Fuling

Qu, Sanyin

Wu, Wenjun

Li, Jing

Ying, Weijiang

Hua, Jianli ^{[1
]}

机构：

[1] E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China

来源：

SYNTHETIC METALS | 2010年 / 160卷 / 15-16期

关键词：

Dye-sensitized solar cells; Diketopyrrolopyrrole; Synthesis; Triphenylamine; Donor-pi-accepter-pi-donor; Chenodeoxycholic acid; NANOCRYSTALLINE TIO2 FILMS; LOW-BAND-GAP; ORGANIC-DYES; CHARGE-TRANSFER; HIGH-EFFICIENCY; MOLECULAR DESIGN; COUMARIN DYES; ENERGY-LEVELS; CONVERSION; OLIGOTHIOPHENE;

D O I：

10.1016/j.synthmet.2010.06.017

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Two new metal-free organic dyes (DPP-I and DPP-II) with diketopyrrolopyrrole (DPP) core were designed and synthesized, in which triphenylamine or N,N-bis(4-methoxyphenyl)benzenamine moieties was used as the electron donor, DPP units as the pi-conjugated bridge, and carboxylic acid group as the electron acceptor. Photophysical and electrochemical properties of two dyes were investigated by UV-vis spectrometry and cyclic voltammetry. Electrochemical measurement data indicate that the tuning of the HOMO and LUMO energy levels can be conveniently accomplished by alternating the donor moiety. The DSSC based on dye DPP-I showed better photovoltaic performance: a maximum monochromatic incident photon-to-current conversion efficiency (IPCE) of 80.6% corresponding to an overall conversion efficiency of 2.68%. Although the power conversion efficiencies are not so high, this work explores new donor-pi-accepter-pi-donor models and the effects of molecular design on optical properties. (C) 2010 Elsevier B.V. All rights reserved.

引用

收藏

页码：1767 / 1773

页数：7

相关论文

共 63 条

[1] Red electroluminescence from a 1,4-diketopyrrolo[3,4-c]pyrrole (DPP)-based conjugated polymer [J].

Beyerlein, T ;

Tieke, B ;

Forero-Lenger, S ;

Brütting, W .

SYNTHETIC METALS, 2002, 130 (02) :115-119

[2] Diketopyrrolopyrrole-containing polyfluorenes: Facile method to tune emission color and improve electron affinity [J].

Cao, Derong ;

Liu, Qilin ;

Zeng, Wenjing ;

Han, Shaohu ;

Peng, Junbiao ;

Liu, Shouping .

MACROMOLECULES, 2006, 39 (24) :8347-8355

[3] Synthesis and characterization of novel red-emitting alternating copolymers based on fluorene and diketopyrrolopyrrole derivatives [J].

Cao, DR ;

Liu, QL ;

Zeng, WJ ;

Han, SH ;

Peng, JB ;

Liu, SP .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (08) :2395-2405

[4] Highly Efficient Light-Harvesting Ruthenium Sensitizer for Thin-Film Dye-Sensitized Solar Cells [J].

Chen, Chia-Yuan ;

Wang, Mingkui ;

Li, Jheng-Ying ;

Pootrakulchote, Nuttapol ;

Alibabaei, Leila ;

Ngoc-le, Cevey-ha ;

Decoppet, Jean-David ;

Tsai, Jia-Hung ;

Graetzel, Carole ;

Wu, Chun-Guey ;

Zakeeruddin, Shaik M. ;

Graetzel, Michael .

ACS NANO, 2009, 3 (10) :3103-3109

[5] Tetrahydroquinoline dyes with different spacers for organic dye-sensitized solar cells [J].

Chen, Ruikui ;

Yang, Xichuan ;

Tian, Haining ;

Sun, Licheng .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2007, 189 (2-3) :295-300

[6] Organic d-π-a dyes for dye-sensitized solar cell [J].

Chen, Zhigang ;

Li, Fuyou ;

Huang, Chunhui .

CURRENT ORGANIC CHEMISTRY, 2007, 11 (14) :1241-1258

[7] Novel organic dyes containing bis-dimethylfluorenyl amino benzo[b]thiophene for highly efficient dye-sensitized solar cell [J].

Choi, Hyunbong ;

Lee, Jae Kwan ;

Song, Kihyung ;

Kang, Sang Ook ;

Ko, Jaejung .

TETRAHEDRON, 2007, 63 (15) :3115-3121

[8] Failure of time-dependent density functional theory for long-range charge-transfer excited states: The zincbacteriochlorin-bacterlochlorin and bacteriochlorophyll-spheroidene complexes [J].

Dreuw, A ;

Head-Gordon, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (12) :4007-4016

[9] The role of para-alkyl substituents on meso-phenyl porphyrin sensitised TiO2 solar cells:: control of the eTiO2/electrolyte+ recombination reaction [J].

Forneli, Amparo ;

Planells, Miquel ;

Sarmentero, Maria Angeles ;

Martinez-Ferrero, Eugenia ;

O'Regan, Brian C. ;

Ballester, Pablo ;

Palomares, Emilio .

JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (14) :1652-1658

[10] Molecular Design of Unsymmetrical Squaraine Dyes for High Efficiency Conversion of Low Energy Photons into Electrons Using TiO2 Nanocrystalline Films [J].

Geiger, Thomas ;

Kuster, Simon ;

Yum, Jun-Ho ;

Moon, Soo-Jin ;

Nazeeruddin, Mohammad K. ;

Graetzel, Michael ;

Nueesch, Frank .

ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (17) :2720-2727

← 1 2 3 4 5 6 7 →