Properties of Cr(C,N) hard coatings deposited in Ar-C2H2-N2 plasma

被引:50
作者
Cekada, M
Macek, M
Merl, DK
Panjan, P
机构
[1] Jozef Stefan Inst, Ljubljana 1000, Slovenia
[2] Univ Ljubljana, Fac Elect Engn, Ljubljana 1000, Slovenia
关键词
hard coatings; high temperature oxidation; ion-plating; sputtering; evaporation;
D O I
10.1016/S0040-6090(03)00328-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Several chromium carbonitride (Cr-(C,N)) coatings were prepared with different C:N ratios by varying the N-2 and C2H2 flow. Chromium nitride (Cr-N) and chromium carbide (Cr-C) coatings were also prepared for comparison. The coatings were deposited in two different ion-plating systems: by reactive evaporation in BAI730M (Balzers) apparatus at high temperature (450 degreesC) and by reactive sputtering in plasma-beam Sputron (Balzers) apparatus at low temperature (200 degreesC). Among mechanical properties microhardness, adhesion (measured by scratch test) and surface roughness were evaluated. Oxidation of the coatings was carried out by heating the samples at temperatures of 750-900 degreesC in an oxygen atmosphere. Crystal structure and microstructure were studied by XRD, TEM and SEM. Chemical State of the elements was observed by XPS. The concentration and depth profiles of the samples oxidized at various temperatures were measured by AES, EDX and GDOES. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:174 / 179
页数:6
相关论文
共 22 条
[1]   Microstructure, stress and mechanical properties of arc-evaporated Cr-C-N coatings [J].
Almer, J ;
Odén, M ;
Håkansson, G .
THIN SOLID FILMS, 2001, 385 (1-2) :190-197
[2]   A CHROMIUM CARBIDE PHASE WITH B1 STRUCTURE IN THIN-FILMS PREPARED BY ION PLATING [J].
BEWILOGUA, K ;
HEINITZ, HJ ;
RAU, B ;
SCHULZE, S .
THIN SOLID FILMS, 1988, 167 (1-2) :233-243
[3]   Comparison of structural and chemical properties of Cr-based hard coatings [J].
Cekada, M ;
Panjan, P ;
Macek, M ;
Smíd, P .
SURFACE & COATINGS TECHNOLOGY, 2002, 151 :31-35
[4]   CHARACTERIZATION AND WEAR-RESISTANCE OF COATINGS IN THE CR-C-N TERNARY-SYSTEM DEPOSITED BY PHYSICAL VAPOR-DEPOSITION [J].
CHOLVY, G ;
DEREP, JL ;
GANTOIS, M .
THIN SOLID FILMS, 1985, 126 (1-2) :51-60
[5]   Evaluation of thin film coatings for erosive-corrosive wear prevention in die casting dies [J].
Gopal, S ;
Lakare, A ;
Shivpuri, R .
SURFACE ENGINEERING, 1999, 15 (04) :297-300
[6]  
Groudeva-Zotova S, 2000, SURF INTERFACE ANAL, V30, P544, DOI 10.1002/1096-9918(200008)30:1<544::AID-SIA814>3.0.CO
[7]  
2-7
[8]  
Hedenqvist P., 1992, Surface Engineering, V8, P39
[9]  
Joint Committee on Powder Diffraction Stan- dards, 1993, JOINT COMMITTEE POWD
[10]   High temperature oxidation of a CrN coating deposited on a steel substrate by ion plating [J].
Lee, DB ;
Lee, YC ;
Kwon, SC .
SURFACE & COATINGS TECHNOLOGY, 2001, 141 (2-3) :227-231