Lipase-catalysed production of biodiesel fuel from some Nigerian lauric oils

被引:97
作者
Abigor, RD [1 ]
Uadia, PO [1 ]
Foglia, TA [1 ]
Haas, MJ [1 ]
Jones, KC [1 ]
Okpefa, E [1 ]
Obibuzor, JU [1 ]
Bafor, ME [1 ]
机构
[1] USDA, Eastern Reg Res Ctr, Wyndmoor, PA 19038 USA
关键词
enzymes; fatty acid ester; renewable fuel; trans-esterification;
D O I
10.1042/0300-5127:0280979
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 [生物化学与分子生物学]; 081704 [应用化学];
摘要
Fatty acids esters were produced from two Nigerian lauric oils, palm kernel oil and coconut oil, by transesterification of the oils with different alcohols using PS30 lipase as a catalyst. In the conversion of palm kernel oil to alkyl esters (biodiesel), ethanol gave the highest conversion of 72%, t-butanol 62%, 1-butanol 42%, n-propanol 42% and iso-propanol 24%, while only 15% methyl ester was observed with methanol. With coconut oil, 1-butanol and iso-butanol achieved 40% conversion, 1-propanol 16% and ethanol 35%, while only traces of methyl esters were observed using methanol. Studies on some fuel properties of palm kernel oil and its biodiesel showed that palm kernel oil had a viscosity of 32.40 mm(2)/s, a cloud point of 28 degreesC and a pour point of 22 degreesC, while its biodiesel fuel had a viscosity of 9.33 mm(2)/s, a cloud point of 12 degreesC and a pour point of 8 degreesC. Coconut oil had a viscosity of 28.58 mm(2)/s, a cloud point of 27 degreesC and a pour point of 20 degreesC, while its biodiesel fuel had a viscosity of 7.34 mm(2)/s, a cloud point of 5 degreesC and a pour point of - 8 degreesC. Some of the fuel properties compared favourably with international biodiesel specifications.
引用
收藏
页码:979 / 981
页数:3
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