Properties of the energy landscape of network models for covalent glasses

被引:18
作者
Schon, JC
Sibani, P
机构
[1] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany
[2] Odense Univ, Inst Fys, DK-5230 Odense M, Denmark
来源
JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL | 1998年 / 31卷 / 40期
关键词
D O I
10.1088/0305-4470/31/40/011
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We investigate the energy landscape of two-dimensional network models for covalent glasses by means of the lid algorithm. For three different particle densities and for a range of network sizes, we exhaustively analyse many configuration space regions enclosing deep-lying energy minima. We extract the local densities of states and of minima, and the number of states and minima accessible below a certain energy barrier, the 'lid'. These quantities show on average a close to exponential growth as a function of their respective arguments. We calculate the configurational entropy for these pockets of states and find that the excess specific heat exhibits a peak at a critical temperature associated with the exponential growth in the local density of states, a feature of the specific heat also observed in real glasses at the glass transition.
引用
收藏
页码:8165 / 8178
页数:14
相关论文
共 28 条
  • [1] ANOMALOUS LOW-TEMPERATURE THERMAL PROPERTIES OF GLASSES AND SPIN GLASSES
    ANDERSON, PW
    HALPERIN, BI
    VARMA, CM
    [J]. PHILOSOPHICAL MAGAZINE, 1972, 25 (01): : 1 - &
  • [2] BOUCHAUD JP, 1997, CONDMAT9702070
  • [3] ANHARMONIC POTENTIALS AND VIBRATIONAL LOCALIZATION IN GLASSES
    BUCHENAU, U
    GALPERIN, YM
    GUREVICH, VL
    SCHOBER, HR
    [J]. PHYSICAL REVIEW B, 1991, 43 (06) : 5039 - 5045
  • [4] CICCOTTI G, 1997, SIMULATION LIQUIDS S
  • [5] ELLIOTT SR, 1990, PHYSICS AMORPHOUS MA
  • [6] FRAUENFELDER H, 1996, PHYSICA D, V107, P2
  • [7] THEORY OF LOW-TEMPERATURE THERMAL-EXPANSION OF GLASSES
    GALPERIN, YM
    GUREVICH, VL
    PARSHIN, DA
    [J]. PHYSICAL REVIEW B, 1985, 32 (10): : 6873 - 6883
  • [8] GUTZOW I, 1995, VITREOUS STATE
  • [9] DIFFUSION IN HIERARCHIES
    HOFFMANN, KH
    SIBANI, P
    [J]. PHYSICAL REVIEW A, 1988, 38 (08): : 4261 - 4270
  • [10] KLOTZ T, IN PRESS EUR J PHYS