Transformation of inorganic sulfur into organic sulfur: A novel photoluminescent 3-D polymeric complex involving ligands in situ formation

被引：70

作者：

Li, D ^{[1
]}

Wu, T ^{[1
]}

机构：

[1] Shantou Univ, Dept Chem, Guangdong 515063, Peoples R China

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 05期

关键词：

D O I：

10.1021/ic0484856

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of CuSCN with acetonitrile and methanol under solvothermal conditions yielded a novel 3-D polymeric photoluminescent complex containing dodecanuclear copper(I) clusters with methyl mercaptide. The synthesis involves in situ generation of ligands, which provides a model reaction to simulate the transformation of inorganic sulfur into organic sulfur under geothermic conditions.

引用

页码：1175 / 1177

页数：3

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