Characteristics comparison of tar from lignite pyrolysis with inherent and simulated moisture for adopting a two-stage gasification process

被引:25
作者
Zhang, Lijuan [1 ,2 ]
Zeng, Xi [2 ,3 ]
Wang, Jiale [1 ,2 ]
Wang, Fang [2 ]
Zhang, Jianling [2 ]
Guo, Minchen [1 ]
Peng, Cuina [4 ]
Wu, Rongcheng [2 ]
Xu, Guangwen [2 ,5 ]
机构
[1] North China Elect Power Univ, Sch Energy Power & Mech Engn, Beijing 102206, Peoples R China
[2] Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
[3] Univ Chinese Acad Sci, Sinodanish Coll, Beijing 100049, Peoples R China
[4] Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Shandong, Peoples R China
[5] Shenyang Univ Chem Technol, Inst Ind Chem & Energy Technol, Shenyang 110142, Liaoning, Peoples R China
关键词
Low rank coal; Two-stage gasification; Fluidized bed; Pyrolysis; Inherent moisture; LOW-RANK COALS; VICTORIAN BROWN-COAL; GAS-PRODUCTION; HERB RESIDUE; BED REACTOR; BIOMASS; TEMPERATURE; GASIFIER; PRODUCTS; WATER;
D O I
10.1016/j.fuel.2018.09.056
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
080707 [能源环境工程]; 082001 [油气井工程];
摘要
To utilize low rank coal cleanly and high efficiently, a new fluidized bed two-stage gasification (FBTSG) process, mainly consisting of a FB pyrolyzer and a transport bed gasifier, has been proposed to treat pressurized coal (below 10 mm) with relatively high moisture for the production of clean fuel gas. In this study, a laboratory FB pyrolysis apparatus was adopted to examine the influence of moisture mode on pyrolysis behavior from 600 degrees C to 900 degrees C, especially in the yield and property of pyrolysis tar. Two common experimental methods in literatures, namely wet coal with inherent moisture and dried coal with the simulated moisture by introducing steam, were systematically analyzed. Compared to the simulated moisture, inherent moisture in coal can facilitate effectively the generation of tar at 700 degrees C and 800 degrees C, and had strong reforming effect on tar conversion to light fraction, leading to more production of light fractions and micro-molecule compounds. All of these differences were much related to the difference in interaction pathway between volatile matter and moisture.
引用
收藏
页码:695 / 708
页数:14
相关论文
共 41 条
[1]
Validation of a continuous combined heat and power (CHP) operation of a two-stage biomass gasifier [J].
Ahrenfeldt, Jesper ;
Henriksen, Ulrik ;
Jensen, Torben K. ;
Gobel, Benny ;
Wiese, Lars ;
Kather, Alphons ;
Egsgaard, Helge .
ENERGY & FUELS, 2006, 20 (06) :2672-2680
[2]
Effects of moisture content and CaO on municipal solid waste pyrolysis in a fixed bed reactor [J].
Chen, Chong ;
Jin, Yuqi ;
Chi, Yong .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2014, 110 :108-112
[3]
Effect of initial moisture content on the yields of oily products from pyrolysis of biomass [J].
Demirbas, A .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2004, 71 (02) :803-815
[4]
Analysis of the Interactions between Moisture Evaporation and Exothermic Pyrolysis of Hazelnut Shells [J].
Di Blasi, C. ;
Galgano, A. ;
Branca, C. ;
Clemente, M. .
ENERGY & FUELS, 2016, 30 (10) :7878-7886
[5]
Oxygen-blown operation of the TwoStage Viking gasifier [J].
Gadsboll, Rasmus Ostergaard ;
Sarossy, Zsuzsa ;
Jorgensen, Lars ;
Ahrenfeldt, Jesper ;
Henriksen, Ulrik Birk .
ENERGY, 2018, 158 :495-503
[6]
Effect of hydrothermal dewatering on the pyrolysis characteristics of Chinese low-rank coals [J].
Ge, Lichao ;
Feng, Hongcui ;
Xu, Chang ;
Zhang, Yanwei ;
Wang, Zhihua .
APPLIED THERMAL ENGINEERING, 2018, 141 :70-78
[7]
PYROLYSIS OF A WOOD-DERIVED MATERIAL - EFFECTS OF MOISTURE AND ASH CONTENT [J].
GRAY, MR ;
CORCORAN, WH ;
GAVALAS, GR .
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1985, 24 (03) :646-651
[8]
Water uptake in biochars: The roles of porosity and hydrophobicity [J].
Gray, Myles ;
Johnson, Mark G. ;
Dragila, Maria I. ;
Kleber, Markus .
BIOMASS & BIOENERGY, 2014, 61 :196-205
[9]
Catalytic steam reforming of biomass tar: Prospects and challenges [J].
Guan, Guoqing ;
Kaewpanha, Malinee ;
Hao, Xiaogang ;
Abudula, Abuliti .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2016, 58 :450-461
[10]
Catalytic upgrading of coal pyrolysis tar over char-based catalysts [J].
Han, Jiangze ;
Wang, Xingdong ;
Yue, Junrong ;
Gao, Shiqiu ;
Xu, Guangwen .
FUEL PROCESSING TECHNOLOGY, 2014, 122 :98-106