Dehydrogenation of ethylbenzene and propane over Ga2O3-ZrO2 catalysts in the presence of CO2

被引:66
作者
Li, Huiyun
Yue, Yinghong
Miao, Changki
Xie, Zaiku
Hua, Weiming [1 ]
Gao, Zi
机构
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[3] Shanghai Res Inst Petrochem Technol, Shanghai 202208, Peoples R China
[4] Anyang Normal Univ, Dept Chem, Anyang 455002, Henan, Peoples R China
基金
中国国家自然科学基金; 上海市自然科学基金;
关键词
dehydrogenation; ethylbenzene; propane; styrene; propene; CO2;
D O I
10.1016/j.catcom.2006.11.034
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ga2O3-ZrO2 catalysts were prepared by a coprecipitation method. The catalysts were characterized by XRD, Raman, DRS, XPS, SEM, EDX, IR, NH3-TPD, CO2-TPD and N-2 adsorption methods. Dehydrogenation of ethylbenzene and propane in the presence of CO2 over these catalysts has been investigated and compared. Ga2O3-ZrO2 catalysts exhibit different catalytic behavior for the two dehydrogenation reactions. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:1317 / 1322
页数:6
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