Green luminescence of the europium chloride: dimethylformamide charge-transfer complex

被引：16

作者：

Dimitriev, OP ^{[1
]}

Kislyuk, VV ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, Inst Semicond Phys, UA-03028 Kiev, Ukraine

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 377卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(03)01121-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A wide emission band located at similar to530 nm was observed upon UV irradiation of the dimethylformamide solution of EuCl3 with excess of the chloride anions in the solution. Intensity of the emission band was found to be several times higher as compared with the emission lines at 590 and 612 nm originating from the trivalent europium ions. The origin of the green emission band is assigned to the divalent europium ions formed as a result of electron transfer from the dimethylformamide (DMFA)/Cl- environment to the Eu3+ cations. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：149 / 155

页数：7

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