Synthesis of new chiral N-heterocyclic carbene-imine ligands and their application to an asymmetric allylic alkylation reaction

被引：144

作者：

Bonnet, LG

Douthwaite, RE ^{[1
]}

Kariuki, BM

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Univ Birmingham, Sch Chem Sci, Birmingham B15 2TT, W Midlands, England

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 21期

关键词：

D O I：

10.1021/om034050z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silver(I) and palladium(II) complexes of new chiral N-heterocyclic carbene (NHC)-imine ligands derived from trans-1,2-diaminocyclohexane have been prepared. These ligands have been applied to a palladium(II)-catalyzed asymmetric allylic alkylation reaction giving a maximum ee of 92%.

引用

页码：4187 / 4189

页数：3

共 52 条

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