Activation of Molecular Oxygen by Anionic Gold Clusters

被引：102

作者：

Woodham, Alex P. ^{[1
]}

Meijer, Gerard ^{[1
]}

Fielicke, Andre ^{[1
]}

机构：

[1] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 18期

关键词：

clusters; gold; nano catalysis; O-O activation; vibrational spectroscopy; BASIS-SETS; CO; OXIDATION; TRANSITION; HYDROGEN; SIZE; ADSORPTION; BINDING; AU-N(-); SITES;

D O I：

10.1002/anie.201108958

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A golden opportunity: Molecular oxygen is found to be converted into a superoxo (O 2 -) species upon complexation to gold-cluster anions containing an even number of Au atoms. Vibrational spectra (see scheme) reveal small variations in the extent of O-O bond activation dependent upon the electron affinity of the parent cluster. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4444 / 4447

页数：4

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