Aryl-Perfluoroaryl Substituted Tetracene: Induction of Face-to-Face π-π Stacking and Enhancement of Charge Carrier Properties

被引：130

作者：

Okamoto, Toshihiro ^{[1
]}

Nakahara, Katsumasa ^{[1
]}

Saeki, Akinori ^{[2
]}

Seki, Shu ^{[2
]}

Oh, Joon Hak ^{[3
]}

Akkerman, Hylke B. ^{[3
]}

Bao, Zhenan ^{[3
]}

Matsuo, Yutaka ^{[1
]}

机构：

[1] Univ Tokyo, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan

[2] Osaka Univ, Grad Sch Engn, Div Appl Chem, Suita, Osaka 5650871, Japan

[3] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA

来源：

CHEMISTRY OF MATERIALS | 2011年 / 23卷 / 07期

基金：

日本科学技术振兴机构;

关键词：

tetracene; aryl-perfluoroaryl interaction; photoconductivity; organic thin-film transistor; crystal engineering; RING POLYAROMATIC HYDROCARBONS; FIELD-EFFECT TRANSISTORS; SOLID-STATE ORDER; CRYSTAL-STRUCTURES; ORGANIC ELECTRONICS; BUILDING-BLOCKS; PHASE-BEHAVIOR; MICROWAVE CONDUCTIVITY; FUNCTIONALIZED ACENES; OPTICAL SPECTROSCOPY;

D O I：

10.1021/cm200356y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

5-Perfluorophenyl-11-phenyltetracene (FPPT) having both aryl (Ar) and perfluoroaryl (FAr) groups has been designed and synthesized to obtain well-defined n-n stacking structure of the tetracene core. Single-crystal X-ray analyses as well as photoconductivity and hole mobility measurements revealed that this strategy is promising for enhancement of the charge carrier properties. © 2011 American Chemical Society.

引用

页码：1646 / 1649

页数：4

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