Vacancy induced p-n homojunctions have been successfully grown in situ from an aqueous solution bath in Pb1-xFexS (x = 0.25 and 0.50) semiconductor nanoparticle films. An abrupt change of DC bias to the substrate during growth has been used as a technique to fabricate p-n junctions. (I-V) and (C-V) measurements confirm the formation of homojunctions in the nanoparticle thin films.